超厚板TC4钛合金电子束焊接接头应力腐蚀敏感性

针对100 mm超厚板TC4钛合金电子束焊接接头，采用慢应变速率拉伸方法评价接头在人造海水中的应力腐蚀敏感性，分析接头的显微组织和断口形貌，对接头的腐蚀机制进行研究. 结果表明，室温条件下应变速率为ε=1×10-6 s-1时，母材在海水中未表现出应力腐蚀敏感性；焊缝上部、中部和下部具有轻微应力腐蚀敏感性. 焊缝在海水中发生阳极溶解，产生氢吸附，导致裂纹的萌生. 同时氢扩散诱导α'相界及α'相内发生位错塞积，进而使裂纹在更低的应力水平下发生扩展.     

喷泉景观的造型设计与模型研究

在分析现有喷泉模拟的基础上，针对喷泉造型的研究相对较少的问题，进行了喷泉造型设计并建模。运用多种数学曲线、曲面方程建立了复杂特殊的喷泉造型模型，并分析喷泉粒子的运动特性建立了喷泉运动模型。采用Visual Studio为编程工具，结合OpenGL技术渲染场景，在Windows XP环境下开发了基于粒子系统的喷泉模拟系统，仿真效果真实。     

Effect of the annealing procedure and the molecular weight on the crystalline phase morphology and thermal properties of polylactide

The thermomechanical properties of poly(lactide) (PLA) are strongly related to its semicrystalline microstructure and morphology. Thermal annealing is a strategy to improve the crystallinity of PLA. However, the different techniques and specimen types needed for each kind of characterization could lead to misleading conclusions. In this work, annealed samples of three PLA grades with different molecular weights were studied by DSC, wide angle X‐ray scattering and polarized optical microscopy (POM) and the results are related to their thermomechanical and impact properties. Special focus is put on the POM results obtained by different approaches and the suitability of each of them to be related to the thermomechanical properties. By annealing medium molecular weight PLA specimens at 140 °C an important increase of the heat distortion temperature was obtained, which was not related to the spherulite size but to the combination of high crystallinity degree together with high α/α′ crystal type ratio. However, the impact properties of annealed PLA decreased with increase in the annealing temperature according to an increment in crystallinity and in the α/α′ crystal ratio. © 2019 Society of Chemical Industry     

High strain rate compressive response of the Cf/SiC composite

Carbon fiber reinforced ceramic owns the properties of lightweight, high fracture toughness, excellent shock resistance, and thus overcomes ceramic's brittleness. The researches on the advanced structure of astronautics, marine have exclusively evaluated the quasi-static mechanical response of carbon fiber reinforced ceramics, while few investigations are available in the open literature regarding elastodynamics. This paper reports the dynamic compressive responses of a carbon fiber reinforced silicon carbide (C_f/SiC) composite (CFCMC) tested by the material test system 801 machine (MTS) and the split Hopkinson pressure bar (SHPB). These tests were to determine the rate dependent compression response and high strain rate failure mechanism of the C_f/SiC composite in in-plane and out-plane directions. The in-plane compressive strain rates are from 0.001 to 2200?s^?1, and that of the out-plane direction are from 0.001 to 2400?s^?1. The compressive stress-strain curves show the C_f/SiC composite has a property of strain rate sensitivity in both directions while under high strain rate loadings. Its compressive stiffness, compressive stress, and corresponding strain are also strain rate sensitive. The compressive damage morphologies after high strain rate impacting show different failure modes for each loading direction. This study provides knowledge about elastodynamics of fiber-reinforced ceramics and extends their design criterion with a reliable evaluation while applying in the scenario of loading high strain rate.     

Biosynthesis of silver nanoparticles in collagen gel improves their medical use in periodontitis treatment

Silver nanoparticles (AgNP) suspensions were biosynthesized by silver ions reduction in the presence of collagen, a nontoxic, organic polymer, intending to improve their medical use in periodontitis treatment. Spectrophotometric measurements showed a time- and concentration-dependent increase of AgNP formation in each suspension variant. Transmission electron microscopy revealed spherical morphology of AgNP in collagen and their mean diameter size was around 30?nm. The particle size distribution and zeta potential values of AgNP in collagen were determined by dynamic light scattering measurements. The surface charge of AgNP in collagen was positive, while commercial AgNP stabilized in citrate had negative surface charge. In vitro cytotoxicity testing of AgNP in collagen showed that they were biocompatible with human gingival fibroblasts in a wider range of concentrations than commercial nanoparticles. The antibacterial activity of AgNP in collagen against two pathogenic strains present in the periodontal pocket was dose-dependent and higher than that of AgNP in citrate. All these results demonstrated that AgNP prepared in collagen gel had improved properties, like small diameter, positive surface charge, high biocompatibility in human gingival fibroblasts, efficiency against bacterial growth and, thus, better therapeutic potential in periodontal disease treatment.     

300M超高强钢在中性盐雾环境中的腐蚀行为及机制

摘要：为了研究300M超高强钢在中性盐雾环境中的腐蚀行为及腐蚀机制，采用失重法，宏观、微观腐蚀形貌分析，三维表面轮廓分析及电化学分析的研究方法，来表征腐蚀实验现象并进行分析。结果表明：300M超高强钢在中性盐雾环境中的腐蚀产物为FeOOH、Fe2O3、Fe(OH)3和Fe3O4；腐蚀速率随着腐蚀时间逐渐降低，腐蚀后期（72h）腐蚀速率降低50%；腐蚀初期以点蚀为主，点蚀坑通过横向扩展，逐渐发展为后期的均匀腐蚀，腐蚀表面形貌呈沟壑状；外腐蚀层对基体的保护能力很弱，Cr元素在锈层靠近基体的一侧偏聚使内腐蚀层具有一定的抗腐蚀性。     

Fabrication of high-purity HfSi2 powder via molten salt-assisted magnesium thermal reduction

In this work, high-purity HfSi₂ powders were successfully fabricated via a molten salt-assisted magnesium thermal reduction method using HfO₂ and Si as raw materials. The effects of reaction temperature and time on the formation of HfSi₂ were systemically investigated. The morphological and phase composition of as-prepared HfSi₂ powders were characterized by scanning electron microscopy, transmission electron microscopy, X-ray diffraction, and nitrogen/oxygen determinator. The results indicated that as-obtained HfSi₂ powders possess the orthorhombic structure with approximately 6.4 μm in size and the oxygen content as low as 0.20%. This work can provide a novel route to fabricate the high-purity transition metal silicides powders.     

相场法模拟GaAs衬底上InGaAs异质结表面形貌

本工作采用相场法模拟GaAs衬底上生长的In_(0.3)Ga_(0.7)As多层异质结构薄膜表面。通过引入多序参量,使用半隐性傅里叶谱方法求解Cahn-Hilliard方程可以求得带缓冲层结构的薄膜表面形貌。计算结果模拟了薄膜生长过程,研究显示,使用In0.15-Ga0.85As缓冲层,厚度从1nm增加到4nm,薄膜表面临界波长从34nm提升到80nm。随着缓冲层的厚度从1nm增加到10nm,使用正弦波表面的模拟结果显示,薄膜表面粗糙度从2.87nm下降到0.43nm,随机叠加波表面的模拟结果也类似,表面粗糙度从1.21nm下降到0.18nm。热力学分析和应变分布分析可以解释缓冲层对薄膜表面形貌演化的作用。该模拟计算方式对设计缓冲层结构有很大的帮助,模拟计算的结果可以与实验相比对。     

基于信息熵与形态学的鸟鸣数据处理

为了探索一种减少训练量并提高精度,且适应于卷积神经网络的预处理方法,以识别鸟鸣为例,基于信息熵以及形态学在图像处理上的应用,根据鸟鸣的间隔性特点,提出新的处理方案。利用形态学将音频片段归类为有效和噪声信号两类;使用加权的方法利用信息熵预测有效数据的分布。仿真结果表明,形态学使数据量减少且信息熵处理使单个数据稀疏化并起到滤波作用,在保持精度甚至精度提高的情况下缩短了训练时间,为卷积神经网络的数据预处理的简化提供了方向。